List of Representative Publications

2010


Coordination of Coenzyme M and Its Derivatives on NiII(tetraazacycle) Complexes: A Model for the Active Site of Methyl Coenzyme M Reductase
Jun-ichi Nishigaki, Tsuyoshi Matsumoto, Kazuyuki Tatsumi
Eur. J. Inorg. Chem., 2010, 31, 5011-5017


Exploring the Limits of Frustrated Lewis Pair Chemistry with Alkynes: Detection of a System that Favors 1,1-Carboboration over Cooperative 1,2-P/B-Addition
Chao Chen, Florian Eweiner, Birgit Wibbeling, Roland Frchlich, Shunsuke Senda, Yasuhiro Ohki, Kazuyuki Tatsumi, Stefan Grimme, Gerald Kehr, Gerhard Erker
Chem. Asian J., 2010, 5, 2199–2208


An Iron(II) Carbonyl Thiolato Complex Bearing 2-Methoxy-Pyridine: A Structural Model of the Active Site of [Fe] Hydrogenase
Soichiro Tanino, Yasuhiro Ohki, Kazuyuki Tatsumi
Chem. Asian J., 2010, 5, 1962-1964


C-H Bond Activation / Borylation of Furans and Thiophenes Catalyzed by a Half-Sandwich Iron N-Heterocyclic Carbene Complex
Tsubasa Hatanaka, Yasuhiro Ohki, Kazuyuki Tatsumi
Chem. Asian J., 2010, 5, 1657-1666


Synthesis of Coordinatively Unsaturated Mesityliron Thiolate Complexes and Their Reactions with Elemental Sulfur
Takayoshi Hashimoto, Yasuhiro Ohki and Kazuyuki Tatsumi
Inorg. Chem., 2010, 49, 6102-6109


Dodecanuclear-Ellipse and Decanuclear-Wheel Nickel(II) Thiolato Clusters with Efficient Femtosecond Nonlinear Absorption
Chi Zhang, Tsuyoshi Matsumoto, Marek Samoc, Simon Petrie, Suci Meng, T. Christopher Corkery, Robert Stranger, Jinfang Zhang, Mark G. Humphrey, Kazuyuki Tatsumi
Angew. Chem. Int. Ed., 2010, 49, 4209-4212


A Model for the CO-Inhibited Form of [NiFe] Hydrogenase: Synthesis of (CO)3Fe(μ-StBu)3Ni {SC6H3-2,6-(mesityl)2} and Reversible CO Addition at the Ni Site
Yasuhiro Ohki, Kazunari Yasumura, Masaru Ando, Satoko Shimokata, Kazuyuki Tatsumi
Proc. Natl. Acad. Sci. U.S.A., 2010, 107, 3994-3997


Synthesis and Reactions of Coordinatively Unsaturated Half-Sandwich Rhodium and Iridium Complexes Having a 2,6-Dimesitylbenzenethiolate Ligand
Mayumi Sakamoto, Yasuhiro Ohki, Kazuyuki Tatsumi
Organometallics, 2010, 29, 1761-1770


A Dinuclear Nickel Complex Modeling of the Nid(II)-Nip(I) State of the Active Site of Acetyl CoA Synthase
Tsuyoshi Matsumoto, Mikinao Ito, Mai Kotera, Kazuyuki Tatsumi
Dalton Trans., 2010, 39, 2995-2997


2009


Evidence for a Rapid Degenerate Hetero-Cope-Type Rearrangement in [Cp*W(S)2S-CH2-CH=CH2]
Florian Eweiner, Shunsuke Senda, Klaus Bergander, Christian Muck-Lichtenfeld, Stefan Grimme, Roland Frohlich, Michiko Aoyama, Hiroyuki Kawaguchi, Yasuhiro Ohki, Tsuyoshi Matsumoto, Gerald Kehr, Kazuyuki Tatsumi, Gerhard Erker
Chem. Asian J., 2009, 4, 1830-1833


Host Plant Genome Overcomes the Lack of a Bacterial Gene for Symbiotic Nitrogen Fixation
Tsuneo Hakoyama, Kaori Niimi, Hirokazu Watanabe, Ryohei Tabata, Junichi Matsubara, Shusei Sato, Yasukazu Nakamura, Satoshi Tabata, Jichun Li, Tsuyoshi Matsumoto, Kazuyuki Tatsumi, Mika Nomura, Shigeyuki Tajima, Masumi Ishizaka, Koji Yano, Haruko Imaizumi-Anraku, Masayoshi Kawaguchi, Hiroshi Kouchi, Norio Suganuma
Nature, 2009, 462, 514-517


Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster
Yasuhiro Ohki, Motosuke Imada, Ayuro Murata, Yusuke Sunada, Shun Ohta, Masaru Honda, Takahiro Sasamori, Norihiro Tokitoh, Motomi Katada, Kazuyuki Tatsumi
J. Am. Chem. Soc., 2009, 131, 13168-13178


Dinuclear Nickel Complexes Modeling the Structure and Function of the Acetyl CoA Synthase Active Site
Mikinao Ito, Mai Kotera, Tsuyoshi Matsumoto, Kazuyuki Tatsumi
Proc. Natl. Acad. Sci. U.S.A., 2009, 106, 11862-11866


Catalytic Hydrogenation of C=O and C=N Bonds via H2 Heterolysis Mediated by Thiolate Complexes of Rhodium and Iridium
Mayumi Sakamoto, Yasuhiro Ohki, Gerald Kehr, Gerhard Erker, Kazuyuki Tatsumi
J. Organomet. Chem., 2009, 694 2820-2824   (invited paper for special issue)


Dithiolate-Bridged Fe-Ni-Fe Trinuclear Complexes Consisting of Fe(CO)3-n(CN)n (n = 0, 1) Components Relevant to the Active Site of [NiFe] Hydrogenase
Satyanarayan Pal, Yasuhiro Ohki, Teppei Yoshikawa, Katsuaki Kuge, Kazuyuki Tatsumi
Chem. Asian J., 2009, 4, 961-968   (invited paper for special issue)


C-H Bond Activation of Decamethylcobaltocene Mediated by a Nitrogenase Fe8S7 P-Cluster Model
Yasuhiro Ohki, Ayuro Murata, Motosuke Imada, Kazuyuki Tatsumi
Inorg. Chem., 2009, 48, 4271-4273


Cationic and Anionic Dinuclear Nickel Complexes [Ni(N2S2)Ni(dtc)]n (n = -1, +1) Modeling the Active Site of Acetyl-CoA Synthase
Yumei Song, Mikinao Ito, Mai Kotera, Tsuyoshi Matsumoto, Kazuyuki Tatsumi
Chem. Lett., 2009, 38, 184-185


A Dithiolate-Bridged (CN))2(CO)Fe-Ni Complex Reproducing the IR Bands of [NiFe] Hydrogenase
Soichiro Tanino, Zilong Li, Yasuhiro Ohki, Kazuyuki Tatsumi
Inorg. Chem., 2009, 48, 2358-2360


Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes
Mikinao Ito, Tsuyoshi Matsumoto, Kazuyuki Tatsumi
Inorg. Chem., 2009, 48, 2215-2223


Structural Models for the Active Site of Acetyl-CoA Synthase: Synthesis of Dinuclear Nickel Complexes Having Thiolate, Isocyanide, and Thiourea on the Nip Site
Mikinao Ito, Mai Kotera, Yumei Song, Tsuyoshi Matsumoto, Kazuyuki Tatsumi
Inorg. Chem., 2009, 48, 1250-1256



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