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Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster
Dinuclear nickel complexes modeling the structure and function of the acetyl CoA synthase active site
Catalytic Hydrogenation of C=O and C=N Bonds via H2 Heterolysis Mediated by Thiolate Complexes of Rhodium and Iridium
C−H Bond Activation of Decamethylcobaltocene Mediated by a Nitrogenase Fe8S7 P-Cluster Model
Cationic and anionic dinuclear nickel complexes [Ni(N2S2)Ni(dtc)]n (n = -1, +1) modeling the active site of acetyl-CoA synthase
A Dithiolate-Bridged (CN))2(CO)Fe-Ni Complex Reproducing the IR Bands of [NiFe] Hydrogenase
Dithiolate-bridged Fe-Ni-Fe Trinuclear Complexes Consisting of Fe(CO)3-n(CN)n (n = 0, 1) Components Relevant to the Active Site of [NiFe] Hydrogenase
Synthesis and Reactions of Mono- and Dinuclear Ni(I) Thiolate Complexes
Structural Models for the Active Site of Acetyl-CoA Synthase: Synthesis of Dinuclear Nickel Complexes Having Thiolate, Isocyanide, and Thiourea on the Nip Site
C-H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene
Reversible Heterolysis of H2 Mediated by an M-S(thiolate) Bond (M = Rh, Ir): A Mechanistic Implication for [NiFe] Hydrogenase
Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes Having Tethered 2,6-Dimesitylphenyl Thiolate
Thiolate-bridged Dinuclear Iron(Tris-Carbonyl)-Nickel Complexes Relevant to the Active Site of [NiFe] Hydrogenase
Molybdenum Trisulfido-Chlorido Anion [MoClS3]-: A Versatile Precursor for Thiomolybdate Derivatives
Synthesis of Ge2NiS4 Clusters and the Thermal Transformation to a Ge4Ni6S12 Cluster
Synthesis of syn-2,4-Dimercapto-1,3,2,4-dithiadigermetane and Its Application for Ge2PdS4 Cluster Synthesis
A Functional Hydrogenase Model: Reversible Interconversion of H2 and H2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium-Germanium Complex
Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium-Ruthenium Complex
Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-cluster, FeMo-co, and FeFe-co of Nitrogenases
Synthesis of Heteroleptic Iron(II) Thiolate Complexes with Weak Iron-Arene Interactions
Mono{hydrotris(mercaptoimidazolyl)borato} Complexes of Manganese(II), Iron(II), Cobalt(II), and Nickel(II) Halides.
Synthesis of Oxo- and Sulfido-Bridged Germanium-Ruthenium Complexes and Reactions on the Chalcogenido Bridges.
Reductive N-N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe3)2}.
Nickel(II) Thiolate Complexes with a Flexible cyclo-{Ni10S20} Framework.
Sulfido-Bridged Dinuclear Molybdenum-Copper Complexes Related to the Active Site of CO Dehydrogenase: [(dithiolate)Mo(O)S2Cu(SAr)]2- (dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, 1,2-S2C2H4)
Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)2(CN)2(μ-SCH2CH2CH2S)Ni(S2CNR2)]- Modeling the Active Site of [NiFe] Hydrogenase
A Facile Method for Synthesis of (R)-(?)-and (S)-(+)-Homocitric Acid Lactones and Related ?-Hydroxy Dicarboxylic Acids from D- or L-Malic Acid.
Molybdenum Carbonyl Complexes with Citrate and Its Relevant Carboxylates.
Synthesis of [2Fe-2S] and [4Fe-4S] Clusters Having Terminal Amide Ligands from an Iron(II).
A Half-Sandwich Ruthenium(II) Complex Containing a Coordinatively Unsaturated 2,6-Dimesitylphenyl Thiolate Ligand.
Synthesis and structural characterization of silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups.
Coordination Chemistry of Silanedithiolato Ligands Derived from Cyclotrisilathiane: Synthesis and Structures of Complexes of Iron(II), Cobalt(II), Copper(I), and Silver(I).
Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dnuclear Complexes.
Synthesis of the P-Cluster Inorganic Core of Nitrogenases.
Copper and silver complexes containing the S(SiMe2S)22- ligand: Efficient entries into heterometallic sulfido clusters.
Unusual Coordination Modes of Arylthiolates in Mo{h5-SC6H3-2,6-(SiMe3)2}{h7-SC6H3-2,6-(SiMe3)2}.
Synthesis and Reactions of Triphenylsilanethiolato Complexes of Manganese(II), Iron(II), Cobalt(II), and Nickel(II).
Synthesis and Reactions of Group 6 Metal Half-Sandwich Complexes of 2,2-Dicyanoethylene-1,1-dichalcogenolates [(Cp*)M{E2C:C(CN)2}2]- (M = Mo, W; E = S, Se).
Alkylation Reactions of [WS4]2- and [(h5-C5Me5)WS3]- with 2,6-Bis(bromomethyl)pyridine: The First Isolation of Bisalkylated Tetrathiometalate WS2{2,6-(SCH2)2(C5H3N)}.
Syntheses and Characterizations of Three-Dimensional Channel-like Polymeric Lanthanide Complexes Constructed by 1,2,4,5-Benzenetetracarboxylic Acid.
Trithiotungsten(VI) Complexes Having Phosphine-Thiolate Hybrid Ligands: Synthesis and Cluster Forming Reactions with CuBr, FeCl2, and [Fe(CH3CN)6](ClO4)2.
Chiral crystallization of a linear two-coordinated palladium(0) complex bearing propeller-shaped bulky phosphine ligands
Sterically protected dipotassium germanedithiolate
Alkynethiolato and Alkyneselenolato Ruthenium Half-Sandwich Complexes: Synthesis, Structures, and Reactions with (h5-C5H5)2Zr.
Synthesis of a Cp complex of tungsten with three different chalcogenido (O2-, S2-, and Se2-) ligands.
Spontaneous Formation of a Diamond-Crown Structure of Re8 Polyselenide and a Cage Structure of Re3 Polytelluride.
1,2,3,4,5,6,7-hexathiagermepanes: Synthesis, structures, and the ring contraction to 1,2,3,4,5-tetrathiagermolanes
Oxidative Additions of cyclo-Octasulfur and cyclo-Octaselenium to the Cobalt(II) Complex of 1,3-Bis(dimethylphosphino)propane (dmpp): Crystal Structures and Spectroscopic Properties of [Co(S2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4.
The First Palladium(0) Complex of a Linear 1,6,11-Triyne. A Reactive Intermediate in the Catalytic Cyclotrimerization of a Triyne.
Ru(II)-catalyzed cycloadditions of 1,6-heptadiynes with alkenes: New synthetic potential of ruthenacyclopentatrienes as biscarbenoids in tandem cyclopropanation of bicycloalkenes and heteroatom-assisted cyclocotrimerization of 1,6-heptadiynes with heterocyclic alkenes. |